Chromic Acid Oxidation of Coal (II) Oxidation Products
نویسندگان
چکیده
منابع مشابه
Chromic Acid Oxidation of Lactic Acid Catalysed by Manganese(II)
B ak o re and N a r a in 1 studied the kinetics of the oxidation of a-hydroxy acids by chromium(VI) and found that addition of Mn(II) decreases the rate of oxidation to one half of that in absence of Mn(II), when the hydrogen ion concentration is in the range 0.1 to 0.4 M. They attributed this to the disproportionation of Cr(IV) by Mn(II) ions. K em p and W a t e r s 2 observed Mn(II) catalysis...
متن کاملChromic Acid Oxidation of Methylaminopyrazole Formamidine in Sulfuric Acid Medium: A Kinetic and Mechanistic Approach
The kinetics of chromic acid oxidation of one of aminopyrazole formamidine derivatives, namely N,N-dimethylN’-(5-methyl-1H-pyrazol-3-yl) formamidine (MAPF)in sulfuric acid solutions has been investigated at constant ionic strength and temperature. The progress of the reaction was followed spectrophotometrically. The reaction showed a first order dependence on [chromic acid] and fractional-first...
متن کاملDirect oxidation of lymphocytes by chromic acid does not induce blastogenesis.
Blastogenic and cytotoxic effects of hexavalent chromium were evaluated by direct, 2 and 20 min oxidation of lymphocytes by 10.0 to 0.0005 mM CrO3 at 0 degrees C. Oxidized cells exhibited concentration-dependent cytotoxicity and the inhibition of tritiated thymidine incorporation rates. When lymphocytes were oxidized first by 1.0 mM periodic acid (H5IO6) and thereafter by 1.0 mM CrO3, the viabi...
متن کاملAscorbic acid and copper in linoleate oxidation. II. Ascorbic acid and copper as oxidation catalysts.
Both ascorbic acid and copper were strong prooxidants in the oxidation of linoleate in a buffered (pH 7.0) aqueous dispersion at 37 degrees C. Minimum concentrations at which catalytic activity was detected were 1.3 x 10(-7) m for copper and 1.8 x 10(-6) m for ascorbic acid. For concentrations up to 10(-3) m, the increase in rate of oxidation with increase in concentration of catalyst was great...
متن کاملBacterial Oxidation of Pyritic Materials in Coal.
Applicability of the manometric method for studying the oxidation of pyritic material in the presence of bacteria has been demonstrated. Resting cells of Ferrobacillus ferrooxidans accelerated the oxidation of coal pyrites and coarsely crystalline marcasite, but were inactive on coarsely crystalline pyrite. Resting cells of Thiobacillus thiooxidans were inactive on all pyrites tested. Oxidation...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Fuel Society of Japan
سال: 1972
ISSN: 0369-3775,2185-226X
DOI: 10.3775/jie.51.344